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Edge Filters vs. Notch Filters for Raman Instrumentation

In Raman spectroscopy applications, Laser Blocking Filters inserted between the sample and the spectrometer are critical to block
the Rayleigh (elastic) scattered light at the laser wavelength and hence allow the relatively weak Raman (inelastic) scattered light to
be measured accurately. There are two main types of thin-film filters that can be used for laser blocking: Edge Filters and Notch Filters.
So how does one answer the question, "How do I choose between an Edge Filter and a Notch Filter for laser line blocking?"

  RazorEdge® Filters   StopLine® Notch Filters  
  Advantages:   Advantages:  
 
  • Steepest possible edge for looking
    at the smallest Stokes shifts
  • Largest blocking of the laser line
    for maximum laser rejection
 
  • Measure Stokes and Anti-Stokes signals
    simultaneously
  • Greater tunability and bandwidth for
    accommodating variable laser lines
 

The graphs below illustrate the relative advantages of the edge and notch filters. The graph on the left shows filter transmission on a
linear scale and illustrates the ability of a Long-Wave-Pass (LWP) edge filter to get extremely close to the laser line. The logarithmic
graph on the right (where Optical Density (OD) is defined to be OD = -log10(Transmission)) shows the increased edge steepness of
an edge filter relative to a notch filter. Increased edge steepness enables a narrower "transition width," which is defined to be the guaranteed maximum spectral separation between the laser line and the transmitting region of the filter spectrum for light normally
incident on the filter. With transition widths below 1% of the laser wavelength (on Semrock U-grade edge filters), these filters don't
need to be angle-tuned!
 
 
 
The graph on the right shows the relative tuning ranges that can be achieved for edge filters and notch filters. Semrock edge filters can be tuned up to 0.3% of the laser wavelength. The filters shift toward shorter wavelengths as the angle of incidence is increased from
0 degrees to about 8 degrees. Semrock notch filters can be tuned up to 1.0% of the laser wavelength. These filters also shift toward shorter wavelengths as the angle of incidence is increased from
0 degrees up to about 14 degrees.



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