Edge Filters vs. Notch Filters for Raman Instrumentation
In Raman spectroscopy
applications, Laser Blocking Filters inserted between the sample and the
spectrometer are critical to block
the Rayleigh (elastic) scattered light at the laser wavelength and hence
allow the relatively weak Raman (inelastic) scattered light to
be measured accurately. There are two main types of thin-film filters
that can be used for laser blocking: Edge Filters and Notch Filters.
So how does one answer the question, "How do I choose between
an Edge Filter and a Notch Filter for laser line blocking?"
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RazorEdge®
Filters |
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StopLine®
Notch Filters |
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Advantages: |
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Advantages: |
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- Steepest
possible edge for looking
at the smallest Stokes shifts
- Largest
blocking of the laser line
for maximum laser rejection
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- Measure Stokes
and Anti-Stokes signals
simultaneously
- Greater
tunability and bandwidth for
accommodating variable laser lines
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The
graphs below illustrate the relative advantages of the edge and notch
filters. The graph on the left shows filter transmission on a
linear scale and illustrates the ability of a Long-Wave-Pass (LWP)
edge filter to get extremely close to the laser line. The logarithmic
graph on the right (where Optical Density (OD) is defined to be OD
= -log10(Transmission)) shows the increased edge steepness of
an edge filter relative to a notch filter. Increased edge steepness
enables a narrower "transition width," which is defined
to be the guaranteed maximum spectral separation between the laser
line and the transmitting region of the filter spectrum for light
normally
incident on the filter. With transition widths below 1% of the laser
wavelength (on Semrock U-grade edge filters), these filters don't
need to be angle-tuned! |
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The
graph on the right shows the relative tuning ranges that can be achieved
for edge filters and notch filters. Semrock edge filters can be tuned
up to 0.3% of the laser wavelength. The filters shift toward shorter
wavelengths as the angle of incidence is increased from
0 degrees to about 8 degrees. Semrock notch filters can be tuned up
to 1.0% of the laser wavelength. These filters also shift toward shorter
wavelengths as the angle of incidence is increased from
0 degrees up to about 14 degrees. |
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